{"id":7435,"date":"2023-09-18T11:23:18","date_gmt":"2023-09-18T15:23:18","guid":{"rendered":"https:\/\/home.hamptonu.edu\/science\/?page_id=7435"},"modified":"2024-06-20T10:13:27","modified_gmt":"2024-06-20T14:13:27","slug":"kunene-bio","status":"publish","type":"page","link":"https:\/\/home.hamptonu.edu\/science\/kunene-bio\/","title":{"rendered":"Kunene Bio"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-page\" data-elementor-id=\"7435\" class=\"elementor elementor-7435\" data-elementor-post-type=\"page\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-65ee502 elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"65ee502\" data-element_type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-d7f8f02\" data-id=\"d7f8f02\" data-element_type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-130358e elementor-widget elementor-widget-text-editor\" data-id=\"130358e\" data-element_type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<h2><b>Department of Chemistry and Biochemistry Faculty<\/b><\/h2><p><img decoding=\"async\" class=\"wp-image-7428 alignright\" style=\"font-weight: inherit\" src=\"https:\/\/home.hamptonu.edu\/science\/wp-content\/uploads\/sites\/47\/2023\/09\/20230912140852-15256-dr._kunene_b_082323-243x300.jpg\" alt=\"\" width=\"172\" height=\"212\" srcset=\"https:\/\/home.hamptonu.edu\/science\/wp-content\/uploads\/sites\/47\/2023\/09\/20230912140852-15256-dr._kunene_b_082323-243x300.jpg 243w, https:\/\/home.hamptonu.edu\/science\/wp-content\/uploads\/sites\/47\/2023\/09\/20230912140852-15256-dr._kunene_b_082323-830x1024.jpg 830w, https:\/\/home.hamptonu.edu\/science\/wp-content\/uploads\/sites\/47\/2023\/09\/20230912140852-15256-dr._kunene_b_082323-768x948.jpg 768w, https:\/\/home.hamptonu.edu\/science\/wp-content\/uploads\/sites\/47\/2023\/09\/20230912140852-15256-dr._kunene_b_082323-1244x1536.jpg 1244w, https:\/\/home.hamptonu.edu\/science\/wp-content\/uploads\/sites\/47\/2023\/09\/20230912140852-15256-dr._kunene_b_082323-1659x2048.jpg 1659w, https:\/\/home.hamptonu.edu\/science\/wp-content\/uploads\/sites\/47\/2023\/09\/20230912140852-15256-dr._kunene_b_082323.jpg 1729w\" sizes=\"(max-width: 172px) 100vw, 172px\" \/><\/p><p><strong>Dr. Tha<span style=\"font-size: 16px\">biso Kunene, <\/span><span style=\"font-size: 16px\">Assistant Professor<\/span><\/strong><\/p><p>Location: Turner Hall 325B<\/p><p>Phone: (757)-727-5837<\/p><p>E-mail: <a href=\"mailto:thabiso.kunene@hamptonu.edu\">thabiso.kunene@hamptonu.edu<\/a><\/p><p>Expertise: (1). Electroanalytical Chemistry, (2). Electrochemical Atomic Layer Deposition, (3). Vapor Phase Synthesis and Atomic Layer Deposition<\/p><p><strong>Education:<\/strong><\/p><ul><li>Postdoctoral Appointee, Argonne National Laboratory, Lemont, IL, 2021 &#8211; 2022<\/li><li>Doctor of Philosophy (Inorganic Chemistry), University of Delaware, Newark, DE, 2021<\/li><li>Bachelor of Arts in Chemistry (Biochemistry), Colby College, Waterville, ME, 2015<\/li><\/ul><p><strong>Research Interests<\/strong><\/p><ul><li>Intersection of molecular, materials and surface chemistry aimed at improving our understanding of functional materials with applications in catalysis.<\/li><li>Electrocatalysis, Electrochemistry, Chemistry of Materials, CO<sub>2<\/sub> Conversion, Vapor Phase Synthesis.<\/li><\/ul><p><strong>Current Research Projects<\/strong><\/p><p>Metal oxide catalysts for CO<sub>2<\/sub> conversion usually comprise of nanocrystalline materials in which the catalytically active sites are few and often undetectable i.e., grain boundaries and defect sites. Consequently, these materials are not amenable to atomic level understanding of electrocatalytic CO<sub>2<\/sub> conversion. Therefore, our main research goal is to prepare rationally designed, supported (Iron, Fe) metal-oxo\/hydroxo and metal-sulfoxo single-site and nanocluster catalysts for operando structure-activity relationships studies in catalytic CO<sub>2<\/sub> conversion and CH<sub>4<\/sub> oxidation. We draw lessons and analogies from traditional organometallic chemistry to inform approaches to understanding and tuning the coordination chemistry of heterogeneous single-site iron-based catalysts supported on polymers and other metal oxides. Our research is informed by vibrational and optical spectroscopic techniques as well as electroanalytical and computational chemistry methods relevant to structure and reaction mechanism elucidation.<\/p><p>Our research addresses three key challenges:<\/p><ul><li>Insights into the structural stability, precision and evolution of catalytically active clusters.<\/li><li>Understanding the phenomena underpinning the interaction of clusters and their support relevant to the geometric and electronic effects around the single-atom (single-site) Fe centers.<\/li><li>Systematic design and synthesis of metal oxo, hydroxo and sulfoxo clusters with tunable electronic structure for applications towards CO<sub>2<\/sub> reduction and H<sub>2<\/sub>O oxidation.<\/li><\/ul><p><strong>Professional Memberships:<\/strong><\/p><ul><li>American Chemical Society (ACS)<\/li><li>National Organization for the Professional Advancement of Black Chemists and Chemical Engineers (NOBCChE)<\/li><li>Materials Research Society (MRS)<\/li><\/ul><p><strong>Selected Publications:<\/strong><\/p><ol><li><strong>Kunene, T<\/strong>., Martinson, A. B. F. Understanding the Unique Optical and Vibrational Signatures of Sequential Infiltration Synthesis Derived Indium Oxyhydroxide Clusters for CO<sub>2<\/sub> Absorption<em>. JVST: A<\/em>. <strong>2023<\/strong>, <em>41<\/em>, 4, 042402<\/li><li><strong>Kunene, T.,<\/strong> Atifi, A, Rosenthal, J. Influence of Surface Composition of AgSn Films on the Selectivity and Electrokinetics of CO<sub>2<\/sub> Reduction in the Presence of Protic Organic [DBU\u2013H]<sup>+<\/sup> <em>ACS Appl. Energy Mater.<\/em> <strong>2021<\/strong>, <em>4<\/em>, 12, 13605\u201313616<\/li><li><strong>Kunene, T<\/strong>., Atifi, A, Rosenthal, J. Selective CO<sub>2<\/sub> Reduction Over Rose\u2019s Metal in the Presence of an Imidazolium Ionic Liquid Electrolyte. <em>ACS Appl. Energy Mater.<\/em><strong><em>2020<\/em><\/strong>, 3, 5, 4193\u20134200<\/li><li><strong>Kunene, T<\/strong>., Xiong, L., Rosenthal, J. Solar-powered synthesis of hydrocarbons from carbon dioxide and water. <em> <strong>2019<\/strong>, 116 (20)<\/em>, 9693-9695<\/li><li>Wang, Y., Suen, NT., <strong>Kunene, T<\/strong>., Stoyko, S., Bobev, S. Synthesis and Structural Characterization of the Zintl Phases Na<sub>3<\/sub>Ca<sub>3<\/sub>TrPn<sub>4<\/sub>, Na<sub>3<\/sub>Sr<sub>3<\/sub>TrPn<sub>4<\/sub>, and Na<sub>3<\/sub>Eu<sub>3<\/sub>TrPn<sub>4<\/sub> (Tr = Al, Ga, In; Pn = P, As, Sb). <em> Solid State Chem. <strong>2017<\/strong>, 249, 160-168<\/em><\/li><\/ol>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>Department of Chemistry and Biochemistry Faculty Dr. Thabiso Kunene, Assistant Professor Location: Turner Hall 325B Phone: (757)-727-5837 E-mail: thabiso.kunene@hamptonu.edu Expertise: (1). Electroanalytical Chemistry, (2). Electrochemical Atomic Layer Deposition, (3). Vapor Phase Synthesis and Atomic Layer Deposition Education: Postdoctoral Appointee, Argonne National Laboratory, Lemont, IL, 2021 &#8211; 2022 Doctor of Philosophy (Inorganic Chemistry), University of Delaware, [&hellip;]<\/p>\n","protected":false},"author":146,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"site-sidebar-layout":"no-sidebar","site-content-layout":"page-builder","ast-site-content-layout":"full-width-container","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"disabled","ast-breadcrumbs-content":"","ast-featured-img":"disabled","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"set","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"_mc_calendar":[],"footnotes":""},"class_list":["post-7435","page","type-page","status-publish","hentry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Kunene Bio - School Of Science<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/home.hamptonu.edu\/science\/kunene-bio\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Kunene Bio - School Of Science\" \/>\n<meta property=\"og:description\" content=\"Department of Chemistry and Biochemistry Faculty Dr. Thabiso Kunene, Assistant Professor Location: Turner Hall 325B Phone: (757)-727-5837 E-mail: thabiso.kunene@hamptonu.edu Expertise: (1). 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